Material Safety Data Sheet
FisherBrand Traceable Conductivity Calibration Standards
ACC# 45384
Section 1 - Chemical Product and Company Identification |
MSDS Name: FisherBrand Traceable Conductivity Calibration Standards
Catalog Numbers:
06-664-24, 09-328-1, 09-328-6
Synonyms:
Potassium chloride aqueous solution.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7732-18-5 |
Water |
64.7 | 231-791-2 |
71-23-8 |
n-Propyl alcohol |
30 | 200-746-9 |
7447-40-7 |
Potassium chloride |
5.3 | 231-211-8 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: clear, colorless liquid. Flash Point: 35.6 deg C.
Warning! Flammable liquid and
vapor. May cause eye, skin, and respiratory tract
irritation. May be harmful if swallowed. May cause central nervous
system depression. May cause dermatitis.
Target Organs: Central nervous system, liver.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may
cause defatting of the skin and dermatitis.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure. May cause gastric
disturbances and electrolytic imbalance.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to
those described for ingestion.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
exposure may cause liver damage.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. If irritation develops, get medi
cal aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water spray to
keep fire-exposed containers cool. Flammable liquid and vapor. An
ASTM D-4206 Standard Test Method for Sustained Burning of Liquid
Mixtures was completed. The findings indicated that it did not
sustain combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
Flash Point: 35.6 deg C ( 96.08 deg F)
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 3; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Avoid ingestion and inhalation. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames. Keep away from heat, sparks and flame. Keep
away from heat and flame.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Water
|
none listed
|
none listed
|
none listed
|
n-Propyl alcohol
|
100 ppm TWA
|
200 ppm TWA; 500 mg/m3 TWA 800 ppm IDLH
|
200 ppm TWA; 500 mg/m3 TWA
|
Potassium chloride
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Water:
No OSHA Vacated PELs are listed for this chemical.
n-Propyl alcohol:
200 ppm TWA; 500 mg/m3 TWA
Potassium chloride:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Viton gloves are recommended.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A NIOSH/MSHA approved or European Standard EN 149 air
purifying respirator with an organic vapor cartridge
or canister may be permissible under certain
circumstances where airborne concentrations are
expected.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: clear, colorless
Odor: alcohol-like
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:Not available.
Molecular Formula:Solution
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Acid chlorides, acid anhydrides, oxidizing agents, potassium
tert-butoxide.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 7732-18-5:
ZC0110000
CAS# 71-23-8:
UH8225000
CAS# 7447-40-7:
TS8050000
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 =
>90 mL/kg;
.
CAS# 71-23-8:
Draize test,
rabbit, eye: 20 mg/24H Moderate;
Inhalation, mouse: LC50 = 48
gm/m3;
Inhalation, mouse: LC50 =
48000 mg/m3;
Oral, mouse: LD50 =
6800 mg/kg;
Oral, rabbit: LD50 =
2825 mg/kg;
Oral, rat: LD50 = 1870
mg/kg;
Oral, rat: LD50 = 2200
mg/kg;
Skin, rabbit: LD50 = 5040
mg/kg;
.
CAS# 7447-40-7:
Draize test,
rabbit, eye: 500 mg/24H Mild;
Oral,
mouse: LD50 = 1500 mg/kg;
Oral,
rat: LD50 = 2600 mg/kg;
.
Carcinogenicity:
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 71-23-8:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7447-40-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
NOT REGULATED FOR DOMESTIC TRANSPORT |
Not Regulated |
Hazard Class: |
XCP |
|
UN Number: |
|
|
Packing Group: |
|
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 71-23-8 is listed on the TSCA inventory.
CAS# 7447-40-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 71-23-8: immediate, fire.
CAS # 7447-40-7: immediate.
Section 313
This material contains Potassium
chloride (listed as Water Dissociable Nitrate Compounds), 5.3%,
(CAS# 7447-40-7) which is subject to the reporting requirements of
Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 71-23-8 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 7447-40-7 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
R 41 Risk of serious damage to eyes.
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 24 Avoid contact with skin.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 39 Wear eye/face protection.
S 7 Keep container tightly closed.
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 71-23-8: 1
CAS# 7447-40-7: 1
Canada - DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 71-23-8 is listed on Canada's DSL List.
CAS# 7447-40-7 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 71-23-8 is listed on the Canadian Ingredient Disclosure List.
CAS# 7447-40-7 is not listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 12/01/1998
Revision #11 Date: 10/29/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.